
{"id":5746,"date":"2024-01-04T14:41:37","date_gmt":"2024-01-04T19:41:37","guid":{"rendered":"https:\/\/spray-sensors.shany.ca\/using-optical-emission-spectroscopy-in-atmospheric-conditions-to-track-the-inflight-reduction-of-plasma-sprayed-tio2%e2%88%92x-feedstock-for-thermoelectric-applications\/"},"modified":"2024-02-22T15:46:11","modified_gmt":"2024-02-22T20:46:11","slug":"using-optical-emission-spectroscopy-in-atmospheric-conditions-to-track-the-inflight-reduction-of-plasma-sprayed-tio2%e2%88%92x-feedstock-for-thermoelectric-applications","status":"publish","type":"post","link":"https:\/\/spraysensors.tecnar.com\/fr\/using-optical-emission-spectroscopy-in-atmospheric-conditions-to-track-the-inflight-reduction-of-plasma-sprayed-tio2%e2%88%92x-feedstock-for-thermoelectric-applications\/","title":{"rendered":"Using optical emission spectroscopy in atmospheric conditions to track the inflight reduction of plasma sprayed TiO2\u2212x feedstock for thermoelectric applications"},"content":{"rendered":"<p>Thermal spray deposition (specifically Atmospheric Plasma Spraying, APS) is a well-established surface coating technology with a broad scope of applications (i.e., insulative coatings, tribological coatings, anti-corrosion coatings, etc.). In addition, there is a constant drive to introduce the APS process into new and emerging fields. One such niche application for APS would be sub-stoichiometric TiO2\u2212x coatings with enhanced thermoelectric performance (compared to the bulk material). The APS process in this context has a unique ability\u2014given the use of hydrogen as a plasma gas\u2014to reduce TiO2\u2212x material during processing. However, to this point, there is neither a reliable nor self-consistent method to assess (nor control by parametric optimization) the inflight reduction of molten oxide particles during processing. This study shows that using Optical Emission Spectroscopy (OES), it can be possible\u2014even in atmospheric conditions\u2014to identify characteristic emission peaks associated with the inflight reduction of TiO2 during APS. Using this OES data, the input spray processing parameters and their influence on coating microstructure and the degree of inflight reduction of the material will be shown. Results suggest under equilibrium conditions only a minimal amount of hydrogen gas is needed in the plasma to fulfill the TiO2 reduction.<\/p>\n<p><a class=\"btn-tec black\" href=\"https:\/\/link.springer.com\/article\/10.1038\/s41598-023-50592-5\" target=\"_blank\" rel=\"noopener\">Link to publication<\/a><\/p>\n<p><em><small>Originally published at Scientific Reports (Volume 14, article number 554, 2024)<br \/>\nBy Georg Mauer, Edward J. Gildersleeve V<\/small><\/em><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Thermal spray deposition (specifically Atmospheric Plasma Spraying, APS) is a well-established surface coating technology with a broad scope of applications [&#8230;]<\/p>\n<p><a class=\"btn btn-secondary understrap-read-more-link\" href=\"https:\/\/spraysensors.tecnar.com\/fr\/using-optical-emission-spectroscopy-in-atmospheric-conditions-to-track-the-inflight-reduction-of-plasma-sprayed-tio2%e2%88%92x-feedstock-for-thermoelectric-applications\/\">Read More&#8230;<\/a><\/p>\n","protected":false},"author":22,"featured_media":5743,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[55],"tags":[],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.2 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Using optical emission spectroscopy in atmospheric conditions to 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technology with a broad scope of applications [...]Read More...\" \/>\n<meta property=\"og:url\" content=\"https:\/\/spraysensors.tecnar.com\/fr\/using-optical-emission-spectroscopy-in-atmospheric-conditions-to-track-the-inflight-reduction-of-plasma-sprayed-tio2%e2%88%92x-feedstock-for-thermoelectric-applications\/\" \/>\n<meta property=\"og:site_name\" content=\"Tecnar Thermal Spray\" \/>\n<meta property=\"article:publisher\" content=\"https:\/\/www.facebook.com\/tecnarautomation\" \/>\n<meta property=\"article:published_time\" content=\"2024-01-04T19:41:37+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2024-02-22T20:46:11+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/spray-sensors.shany.ca\/wp-content\/uploads\/2024\/02\/SpraySensors-800x500-18.png\" \/>\n\t<meta property=\"og:image:width\" content=\"800\" \/>\n\t<meta property=\"og:image:height\" content=\"500\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/png\" \/>\n<meta name=\"author\" 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